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The shear Modulus of synthetic diamond, which ranges from 440 to 470 GPa (Azo tech information), is almost 15 times higher than that of Silica, which ranges from 27.9 to 32.3 (Azo tech spec.). According to this information and considering the mechanical shear behaviour of the analogous hybrid materials based on silica nanoparticles (Aversa et al. Patrice Evra France Jersey , 2016), the behaviour of the variation of the shear modulus as a function of the diamond nanoparticles volume fraction in the hybrid material could be evaluated Fig. 5.


According to Aversa et al. (2016), strong plasticization is induced by the physiological solutions sorption in the hybrid pHEMA-nanosilica composite.


It has been described by Aversa et al. (2016; 2009) that the measured shear modulus of the Nanosilica hybrid composites at different filler content was not described by the classical Halpin and Kardos (1976) equation that is commonly utilized for the particulate composites. The hybrid nano-composites showed a linear dependency at increasing contents of nanosilica filler. This occurrence confirmed the hybrid nature of the nanosilica filled pHEMA.


At nano-diamond volumetric fractions ranging from 2 to and 5%, the shear moduli were comparable to those of the cortical bone (10-20 GPa Olivier Giroud France Jersey , reported as grey area in Fig. 5). Similar results have been described by Aversa et al. (2016; 2009) to occur for nanosilica hybrids at higher loading ranging from 15 to 30% by volume.


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Methacrylate (pHEMA) filled with detonation nanodiamonds could be identified as a biomimetic biomaterial at filler concentration up to 5% by volume. Moreover, this glassy hybrid material swells to rubber in presence of aqueous physiological solution picking-up more than 40% of water. At very low levels of nano-diamond loading, the mechanical behaviour of the proposed hybrid materials could be comparable with that of bone when in the glassy state, or to that of cartilage and ligaments when in the rubbery state following water sorption.


The use as scaffolds of these mechanically compatible hybrid hydrogels is expected to improve the adaptation mechanisms of the bone by introducing an active interface that could ameliorate biomimetics by correctly reproducing cartilage and ligaments biomechanical functions (Schwartz-Dabney and Dechow N'Golo Kante France Jersey , 2003; Perillo et al., 2010; Apicella et al., 2010; 2011; 2015; Aversa et al., 2016; 2009).


Adaptive properties of bone could benefit of use of biomechanically compatible and bioactive scaffold biomaterials associated to. Cheap Jerseys Replica NFL Jerseys Replica Hockey Jerseys Sale Replica Sports Jerseys Replica Baseball Jerseys Online Cheap Replica Football Jerseys Cheap Replica Jerseys From China Cheap Replica College Jerseys China Cheap Replica Basketball Jerseys Cheap Replica Jerseys Sale